5A2-SC8
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Ionizable lipid for LNP and nucleic-acid delivery research.
Cl-4A3-LNSC8 represents a novel class of thiourea-functionalized ionizable lipids engineered for selective organ-targeted mRNA delivery. Its core innovation lies in an anion-coordination strategy, where the parent lipid, 4A3-LNSC8, binds chloride ions (Cl⁻) via hydrogen-bonding interactions with its thiourea groups. This binding event is not merely structural but functionally critical, as it induces a significant shift in the surface pKa of the resulting lipid nanoparticles (LNPs) from approximately 5.54 to 8.79. This pKa modulation is the key mechanism that redirects the organotropism of the LNPs upon systemic administration. While the unmodified 4A3-LNSC8 LNPs preferentially deliver mRNA to the liver, Cl-4A3-LNSC8 LNPs effectivelyreprogram this tropism, enabling highly efficient mRNA delivery to secondary lymphoid organs (SLOs), particularly the spleen and lymph nodes. This platform demonstrates remarkable efficacy, achieving up to 65.7% gene editing efficiency in splenic macrophages in vivo, significantly outperforming benchmark delivery systems. Furthermore, by leveraging the coordination with different halides, such as iodine for computed tomography (CT) contrast, the system can be adapted for dual-modal theranostic applications, enabling simultaneous lymphatic metastasis imaging and therapeutic mRNA delivery.
| CAS No. | Not available |
| Chemical Name | Cl-4A3-LNSC8 |
| Synonyms | Cl 4A3 LNSC8 |
| SMILES | CCCCCCCCSCC(C)C(=O)OCCNC(=S)NCCOC(=O)CCN(CCCN(C)CCCN(CCC(=O)OCCNC(=S)NCCOC(=O)C(C)CSCCCCCCCC)CCC(=O)OCCN1[Cl-]N(CCOC(=O)C(C)CSCCCCCCCC)C1=S)CCC(=O)OCCNC(=S)NCCOC(=O)C(C)CSCCCCCCCC |
| Formula | C87H163O16ClN11S8- |
| M.Wt | 1,911.25 |
| Purity | ELSD-HPLC>95% |
| Storage | Pure form: −20 °C, 1 year; In solvent: −80 °C, 6 months; −20 °C, 1 month. Sealed and protected from light. |
| Shipping condition | Ships from Shanghai. Pure lipid is stable during ice-pack transport. |
| Publication | Not available |
The product molecular weight is prefilled when available and remains editable. Confirm solvent compatibility and solubility before preparation.
Solvent volumes update from the molecular weight above.
| Mass | 1 mM | 5 mM | 10 mM |
|---|---|---|---|
| 10 mg | 5.2322 mL | 1.0464 mL | 523.22 μL |
| 25 mg | 13.0804 mL | 2.6161 mL | 1.3080 mL |
| 50 mg | 26.1609 mL | 5.2322 mL | 2.6161 mL |
| 100 mg | 52.3218 mL | 10.4644 mL | 5.2322 mL |
| 250 mg | 130.8044 mL | 26.1609 mL | 13.0804 mL |
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